TY - JOUR UR - http://stacks.iop.org/1742-6596/712/i=1/a=012032 T1 - Hydride phase formation in carbon supported palladium hydride nanoparticles by in situ EXAFS and XRD A1 - A L Bugaev and A A Guda and K A Lomachenko and A Lazzarini and V V Srabionyan and J G Vitillo and A Piovano and E Groppo and L A Bugaev and A V Soldatov and V P Dmitriev and R Pellegrini and J A van Bokhoven and C Lamberti Y1 - 2016 SP - 012032 JF - Journal of Physics: Conference Series VL - 712 IS - 1 SN - 1742-6596 N2 - In the current work we present a detailed analysis of the hydride phase formation in industrial Pd/C nanocatalysts by means of combined in situ X-ray absorption spectroscopy (EXAFS), X-ray diffraction (XRD) and volumetric measurements for the temperatures from - 10 to 50 °C in the hydrogen pressure range from 0 to 1000 mbar. α- and β- hydride phases are clearly distinguished in XRD. For the first time, H/Pd atomic ratio were obtained by theoretical fitting of the near-edge region of the absorption spectra (XANES) and compared with volumetric measurements. ER -