Метал-органические каркасные структуры
Метал-органические каркасные структуры

Метал-органические каркасные структуры


Высокопористые материалы, которые разрабатываются в качестве топливных баков для водородных или метановых двигателей будущего могут хранить гораздо большее количество газа, чем предполагалось ранее.

Металлоорганические каркасные структуры [metal-organic frameworks (MOF)] представляют собой координационные полимеры, в которых ионы металлов связаны друг с другом с помощью полидентатных лигандов-линкеров. Такой дизайн позволяет получить материалы с большими порами, открытыми внутренними каналами и большой площадью внутренней поверхности, пригодной для адсорбции молекул, в первую очередь – газов.

По направлению работают



Исследования ведутся в сотрудичестве с


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Публикации по направлению


Всего отобрано 18 публикаций с суммарным значением Impact-factor = 62.126

1. Guda, A. A.; Guda, S. A.; Lomachenko, K. A.; Soldatov, M. A.; Pankin, I. A.; Soldatov, A. V.; Braglia, L.; Bugaev, A. L.; Martini, A.; Signorile, M.; Groppo, E.; Piovano, A.; Borfecchia, E.; Lamberti, C. "Quantitative structural determination of active sites from in situ and operando XANES spectra: From standard ab initio simulations to chemometric and machine learning approaches" Catalysis Today 2019 in press (Impact-factor: 4.667) DOI: 10.1016/j.cattod.2018.10.071

2. Bugaev, et al. "Formation and growth of Pd nanoparticles in UiO-67 MOF by in situ EXAFS" Radiation Physics and Chemistry 2019 accepted (Impact-factor: 1.435)

3. Stubbs, A.W., Braglia, L., Borfecchia, E., Meyer, R.J., Román-Leshkov, Y., Lamberti, C., Dincǎ, M. "Selective Catalytic Olefin Epoxidation with Mn(II)-Exchanged MOF-5" ACS Catalysis 2018 8 (1) 596-601 (Impact-factor: 10.614) DOI: 10.1021/acscatal.7b02946  

4. M. Signorile, A. Damin, F. Bonino, V. Crocellà, G. Ricchiardi, C. Lamberti, and S. Bordiga "Computational assessment of relative sites stabilities and site-specific adsorptive properties of Titanium Silicalite-1" Journal of Physical Chemistry C 2018 122 (3) 1612-1621 (Impact-factor: 4.536) DOI: 10.1021/acs.jpcc.7b10104

5. S. Waitschat, D. Fröhlich, H. Reinsch, H. Terraschke, K. A. Lomachenko, C. Lamberti, H. Kummer, T. Helling, M. Baumgartner, S. Henninger and N. Stock "Synthesis of M-UiO-66 (M = Zr, Ce or Hf) employing 2,5-pyridinedicarboxylic acid as a linker: Defect chemistry, framework hydrophilisation and sorption properties" Dalton Transactions 2018 47 1062-1070 (Impact-factor: 4.029) DOI: 10.1039/C7DT03641H

6. A.L. Bugaev, A.A. Guda, K.A. Lomachenko, E.G. Kamyshova, M.A Soldatov, G. Kaur, S. Øien-Ødegaard, L. Braglia, A. Lazzarini, M. Manzoli, S. Bordiga, U. Olsbye, K. Petter Lillerud, A.V Soldatov and C. Lamberti "Operando study of palladium nanoparticles inside UiO-67 MOF for catalytic hydrogenation of hydrocarbons" Faraday Discussions 2018 208 287-306 (Impact-factor: 3.427) DOI: 10.1039/C7FD00224F  

7. S. Smolders, K.A. Lomachenko, B. Bueken, A. Struyf, A.L. Bugaev, C. Atzori, N. Stock, C. Lamberti, M. B.J. Roeffaers, D. De Vos "Unravelling the redox-catalytic behavior of Ce4+-MOFs: a XAS study" ChemPhysChem 2018 19 (4) 373-378 (Impact-factor: 3.138) DOI: 10.1002/cphc.201700967  

8. M. Mortén, Ł. Mentel, A. Lazzarini, I. A. Pankin, C. Lamberti, S. Bordiga, V. Crocella, S. Svelle, K. P. Lillerud, U. Olsbye "A systematic study of isomorphically substituted H-MeAlPO-5 materials for the Methanol to Hydrocarbons (MTH) reaction" ChemPhysChem 2018 19 (4) 484-495 (Impact-factor: 3.075) DOI: 10.1002/cphc.201701024

9. Yulia Podkovyrina, Vera Butova, Elena Bulanova, Andriy Budnyk, Maria Kremennaya, Alexander Soldatov and Carlo Lamberti "Characterization of local atomic structure in Co/Zn based ZIFs by XAFS" Journal of Physics: Conference Series 2018 987    

10. E. Gallo, E. Gorelov, A.A. Guda, A.L. Bugaev, F. Bonino, E. Borfecchia, G. Ricchiardi, D. Gianolio, S. Chavan, C. Lamberti "Effect of Molecular Guest Binding on the d–d Transitions of Ni2+ of CPO-27-Ni: A Combined UV–Vis, Resonant-Valence-to-Core X-ray Emission Spectroscopy, and Theoretical Study" Inorganic Chemistry 2017 56 (23) 14408-14425 (Journal Cover) (Impact-factor: 4.857) DOI: 10.1021/acs.inorgchem.7b01471

11. L. Braglia, E. Borfecchia, L. Maddalena, S. Øien, K. A. Lomachenko, A. L. Bugaev, S. Bordiga, A. V. Soldatov, K. P. Lillerud, C. Lamberti "Exploring structure and reactivity of Cu sites in functionalized UiO-67 MOFs" Catalysis Today 2017 283 (1) 89–103 (Impact-factor: 4.312) DOI: 10.1016/j.cattod.2016.02.039  

12. L. Braglia, E. Borfecchia, A. Martini, A. L. Bugaev, A. V. Soldatov, S. Øien-Ødegaard, B. T. Lønstad-Bleken, U. Olsbye, K. P. Lillerud, K. A. Lomachenko, G. Agostini, M. Manzoli and C. Lamberti "The duality of UiO-67-Pt MOFs: connecting treatment conditions and encapsulated Pt species by operando XAS" Physical Chemistry Chemical Physics 2017 19 27489-27507 (Impact-factor: 4.123) DOI: 10.1039/C7CP05185A

13. V.V. Butova, A.P. Budnyk, A.A. Guda, K.A. Lomachenko, A.L. Bugaev, A.V. Soldatov, S.M. Chavan, S. Oien-Odegaard, U. Olsbye, K.P. Lillerud, C. Atzori, S. Bordiga, C. Lamberti "Modulator effect in UiO-66-NDC (1, 4-naphthalenedicarboxilic acid) synthesis and comparison with UiO-67-NDC isoreticular MOFs" Crystal Growth & Design 2017 17 (10) 5422–5431 (Journal Cover) (Impact-factor: 4.055) DOI: 10.1021/acs.cgd.7b00892    

14. L. Braglia, E. Borfecchia, K. A. Lomachenko, A. L. Bugaev, A. A. Guda, A. V. Soldatov, B. T. Lønstad Bleken, S. Øien, U. Olsbye, K. P. Lillerud, S. Bordiga, G. Agostini, M. Manzoli, C. Lamberti "Tuning Pt and Cu sites population inside functionalized UiO-67 MOF by controlling activation conditions" Faraday Discuss 2017 201 277-298 (Impact-factor: 3.544) DOI: 10.1039/C7FD00024C  

15. V.V. Butova, A.P. Budnyk, E.A. Bulanova, C. Lamberti, A.V. Soldatov "Hydrothermal synthesis of high surface area ZIF-8 with minimal use of TEA" Solid State Sciences 2017 69 13–21 (Impact-factor: 2.041) DOI: 10.1016/j.solidstatesciences.2017.05.002  

16. V.V. Butova, M.A. Soldatov, A.A. Guda, K.A. Lomachenko, and C. Lamberti "Metal-Organic Frameworks: Structure, Properties, Synthesis, and Characterization" Russ. Chem. Rev. 2016 85 (3) 280-307 (Impact-factor: 2.868) DOI: 10.1070/RCR4554    

17. Vera V. Butova, Andrey P. Budnik, Elena A. Bulanova and Alexander V. Soldatov "New microwave-assisted synthesis of ZIF-8" Mendeleev Commun. 2016 26 43–44 (Impact-factor: 1.405) DOI: 10.1016/j.mencom.2016.01.017    

18. A. A. Guda, S. A. Guda, M. A. Soldatov, K. A. Lomachenko, A. L. Bugaev, C. Lamberti, W. Gawelda, C. Bressler, G. Smolentsev, A. V. Soldatov and Y. Joly "Finite difference method accelerated with sparse solvers for structural analysis of the metal-organic complexes" Journal of Physics: Conference Series 2016 712 (1) 012004 DOI: 10.1088/1742-6596/712/1/012004