Metal-organic Frameworks (MOFs)
Metal-organic frameworks (MOFs) are compounds consisting of metal ions or clusters coordinated to organic molecules to form one-, two-, or three-dimensional structures that can be porous. The organic molecules included are sometimes referred to as "struts", and include such examples as 1,4-benzenedicarboxylic acid (BDC).
More formally, a metal–organic framework is a coordination network with organic ligands containing potential voids. A coordination network is a coordination compound extending, through repeating coordination entities, in one dimension, but with cross-links between two or more individual chains, loops, or spiro-links, or a coordination compound extending through repeating coordination entities in two or three dimensions; and finally a coordination polymer is a coordination compound with repeating coordination entities extending in one, two, or three dimensions.
In some cases, the pores are stable during elimination of the guest molecules (often solvents) and could be used for the storage of gases such as hydrogen and carbon dioxide. Other possible applications of MOFs are in gas purification, in gas separation, in catalysis and as sensors
This project is succesfull thanks to these guys
Who worked in close collaboration with
Some publications
1.
Andrei A. Tereshchenko, Vera V. Butova, Alexander A. Guda, Olga A. Burachevskaya, Aram L. Bugaev, Aleksei N. Bulgakov, Alina A. Skorynina, Yury V. Rusalev, Ilya V. Pankov, Vadim A. Volochaev, Majd Al-Omoush, Ilya V. Ozhogin, Gennadii S. Borodkin, and Alexander V. Soldatov "Rational Functionalization of UiO-66 with Pd Nanoparticles: Synthesis and In Situ Fourier-Transform Infrared Monitoring "
Inorganic Chemistry
2022
61
(9)
3875-3885
(Impact-factor: 4.93 )
DOI: 10.1021/acs.inorgchem.1c03340
2.
Vera V. Butova, Olga A. Burachevskaya, Vitaly A. Podshibyakin, Evgenii N. Shepelenko, Andrei A. Tereshchenko, Svetlana O. Shapovalova, Oleg I. Il’, Vladimir A. Bren’ and Alexander V. Soldatov "Photoswitchable Zirconium MOF for Light-Driven Hydrogen Storage"
Polymers
2021
3
(22)
4052
(Impact-factor: 4.329 )
DOI: 10.3390/polym13224052
3.
Pnevskaya A. Y., Bugaev A. L., Tereshchenko A. A., Soldatov A. V. "Experimental and theoretical investigation of ethylene and 1-MCP binding sites in HKUST-1 metal-organic framework"
The Journal of Physical Chemsitry C
2021
125
(40)
22295–22300 (Journal cover)
(Impact-factor: 4.126 )
DOI: 10.1021/acs.jpcc.1c06503
4.
N. Van Velthoven, M. Henrion, J. Dallenes, A. Krajnc, A.L. Bugaev, P. Liu, S. Bals, A.V. Soldatov, G. Mali, D.E. De Vos "S,O-Functionalized Metal-Organic Frameworks as Heterogeneous Single-Site Catalysts for the Oxidative Alkenylation of Arenes via C-H activation"
ACS Catalysis
2020
10
(9)
5077-5085
(Impact-factor: 13.084 )
DOI: 10.1021/acscatal.0c00801
5.
Ivan E. Gorban, Mikhail A. Soldatov, Vera V. Butova, Pavel V. Medvedev, Olga A. Burachevskaya, Anna Belanova, Peter Zolotukhin, and Alexander V. Soldatov "L-Leucine Loading and Release in MIL-100 Nanoparticles"
Int. J. Mol. Sci.
2020
21
(24)
9758
(Impact-factor: 4.556 )
DOI: 10.3390/ijms21249758
6.
Butova, V.V., Burachevskaya, O.A., Ozhogin, I.V., Borodkin, G.S., Starikov, A.G., Bordiga, S., Damin, A., Lillerud, K.P., Soldatov, A.V. "UiO-66 type MOFs with mixed-linkers - 1,4-Benzenedicarboxylate and 1,4-naphthalenedicarboxylate: Effect of the modulator and post-synthetic exchange"
Microporous and Mesoporous Materials
2020
305
110324
(Impact-factor: 4.551 )
DOI: 10.1016/j.micromeso.2020.110324
7.
E.G. Kamyshova, A.A. Skorynina, A. L. Bugaev, C. Lamberti, A.V. Soldatov "Formation and growth of Pd nanoparticles in UiO-67 MOF by in situ EXAFS"
Radiation Physics and Chemistry
2020
175
108144
(Impact-factor: 2.858 )
DOI: 10.1016/j.radphyschem.2019.02.003
8.
Kirichkov M.V., Bugaev A.L., Skorynina A.A., Butova V.V., Budnyk A.P., Guda A.A., Trigub A.L., Soldatov A.V. "In situ time-resolved decomposition of β-hydride phase in palladium nanoparticles coated with metal-organic framework"
Metals
2020
10
(6)
810
(Impact-factor: 2.259 )
DOI: 10.3390/met10060810
9.
A.L. Bugaev, A.A. Skorynina, L. Braglia, K.A. Lomachenko, A.A. Guda, A. Lazzarini, S. Bordiga, U. Olsbye, K.P. Lillerud, A.V. Soldatov, C. Lamberti "Evolution of Pt and Pd species in functionalized UiO-67 metal-organic frameworks"
Catalysis Today
2019
336
33-39
(Impact-factor: 4.888 )
DOI: 10.1016/j.cattod.2019.03.054
10.
Guda, A. A.; Guda, S. A.; Lomachenko, K. A.; Soldatov, M. A.; Pankin, I. A.; Soldatov, A. V.; Braglia, L.; Bugaev, A. L.; Martini, A.; Signorile, M.; Groppo, E.; Piovano, A.; Borfecchia, E.; Lamberti, C. "Quantitative structural determination of active sites from in situ and operando XANES spectra: From standard ab initio simulations to chemometric and machine learning approaches"
Catalysis Today
2019
336
3-21
(Impact-factor: 4.888 )
DOI: 10.1016/j.cattod.2018.10.071
11.
V.V. Butova, A.P. Budnyk, K.M. Charykov, K.S. Vetlitsyna-Novikova, A.L. Bugaev, A.A. Guda, A. Damin, S.M. Chavan, S. Øien-Ødegaard, K.P. Lillerud, A.V. Soldatov, C. Lamberti "Partial and Complete Substitution of the 1, 4-Benzenedicarboxylate Linker in UiO-66 with 1, 4-Naphthalenedicarboxylate: Synthesis, Characterization, and H2-Adsorption Properties"
Inorganic Chemistry
2019
58
(2)
1607–1620
(Impact-factor: 4.85 )
DOI: 10.1021/acs.inorgchem.8b03087
12.
T. Lastovina, A. Budnyk, Y. Pimonova, A. Bugaev, V. Dmitriev "Thermally-induced arrangement of cobalt and iron in the ZIF-derived Fe,Co,Zn-N/C catalysts for the oxygen reduction reaction"
International Journal of Hydrogen Energy
2019
(Impact-factor: 4.084 )
DOI: 10.1016/j.ijhydene.2019.07.022
13.
Pimonova, Y. A., Budnyk, A. P., Weldegebriel, Y., Bugaev, A. L., Lastovina, T. A. "Iron-/nitrogen-doped electrocatalytically active carbons for the oxygen reduction reaction with low amounts of cobalt"
ACS Omega
2019
4
(22)
19548-19555
(Impact-factor: 2.584 )
DOI: 10.1021/acsomega.9b01534
14.
A.L. Bugaev, A.A. Skorynina, E.G. Kamyshova, K.A. Lomachenko, A.A. Guda, A.V. Soldatov, C. Lamberti "In situ X-ray absorption spectroscopy data during formation of active Pt- and Pd-sites in functionalized UiO-67 metal-organic frameworks"
Data in Brief
2019
25
104280
DOI: 10.1016/j.dib.2019.104280
15.
K. A. Lomachenko, J. Jacobsen, A. L. Bugaev, C. Atzori,
F. Bonino, S. Bordiga, N. Stock, and C. Lamberti "Exact stoichiometry of Ce(x)Zr(6-x) cornerstones in mixedmetal UiO-66 MOFs revealed by EXAFS spectroscopy"
Journal of the American Chemical Society
2018
140
(50)
17379-17383
(Impact-factor: 14.357 )
DOI: 10.1021/jacs.8b10343
16.
Stubbs, A.W., Braglia, L., Borfecchia, E., Meyer, R.J., Román-Leshkov, Y., Lamberti, C., Dincǎ, M. "Selective Catalytic Olefin Epoxidation with Mn(II)-Exchanged MOF-5"
ACS Catalysis
2018
8
(1)
596-601
(Impact-factor: 10.614 )
DOI: 10.1021/acscatal.7b02946
17.
M. Signorile, A. Damin, F. Bonino, V. Crocellà, G. Ricchiardi, C. Lamberti, and S. Bordiga "Computational assessment of relative sites stabilities and site-specific adsorptive properties of Titanium Silicalite-1"
Journal of Physical Chemistry C
2018
122
(3)
1612-1621
(Impact-factor: 4.536 )
DOI: 10.1021/acs.jpcc.7b10104
18.
S. Waitschat, D. Fröhlich, H. Reinsch, H. Terraschke, K. A. Lomachenko, C. Lamberti, H. Kummer, T. Helling, M. Baumgartner, S. Henninger and N. Stock "Synthesis of M-UiO-66 (M = Zr, Ce or Hf) employing 2,5-pyridinedicarboxylic acid as a linker: Defect chemistry, framework hydrophilisation and sorption properties"
Dalton Transactions
2018
47
1062-1070
(Impact-factor: 4.029 )
DOI: 10.1039/C7DT03641H
19.
A.L. Bugaev, A.A. Guda, K.A. Lomachenko, E.G. Kamyshova, M.A Soldatov, G. Kaur, S. Øien-Ødegaard, L. Braglia, A. Lazzarini, M. Manzoli, S. Bordiga, U. Olsbye, K. Petter Lillerud, A.V Soldatov and C. Lamberti "Operando study of palladium nanoparticles inside UiO-67 MOF for catalytic hydrogenation of hydrocarbons"
Faraday Discussions
2018
208
287-306
(Impact-factor: 3.427 )
DOI: 10.1039/C7FD00224F
20.
M. Mortén, Ł. Mentel, A. Lazzarini, I. A. Pankin, C. Lamberti, S. Bordiga, V. Crocella, S. Svelle, K. P. Lillerud, U. Olsbye "A systematic study of isomorphically substituted H-MeAlPO-5 materials for the Methanol to Hydrocarbons (MTH) reaction"
ChemPhysChem
2018
19
(4)
484-495
(Impact-factor: 3.138 )
DOI: 10.1002/cphc.201701024
21.
S. Smolders, K.A. Lomachenko, B. Bueken, A. Struyf, A.L. Bugaev, C. Atzori, N. Stock, C. Lamberti, M. B.J. Roeffaers, D. De Vos "Unravelling the redox-catalytic behavior of Ce4+-MOFs: a XAS study"
ChemPhysChem
2018
19
(4)
373-378
(Impact-factor: 3.138 )
DOI: 10.1002/cphc.201700967
22.
Yulia Podkovyrina, Vera Butova, Elena Bulanova, Andriy Budnyk, Maria Kremennaya, Alexander Soldatov and Carlo Lamberti "Characterization of local atomic structure in Co/Zn based ZIFs by XAFS"
Journal of Physics: Conference Series
2018
987
012031
DOI: 10.1088/1742-6596/987/1/012031
23.
E. Gallo, E. Gorelov, A.A. Guda, A.L. Bugaev, F. Bonino, E. Borfecchia, G. Ricchiardi, D. Gianolio, S. Chavan, C. Lamberti "Effect of Molecular Guest Binding on the d–d Transitions of Ni2+ of CPO-27-Ni: A Combined UV–Vis, Resonant-Valence-to-Core X-ray Emission Spectroscopy, and Theoretical Study"
Inorganic Chemistry
2017
56
(23)
14408-14425 (Journal Cover)
(Impact-factor: 4.857 )
DOI: 10.1021/acs.inorgchem.7b01471
24.
V.V. Butova, A.P. Budnyk, A.A. Guda, K.A. Lomachenko, A.L. Bugaev, A.V. Soldatov, S.M. Chavan, S. Oien-Odegaard, U. Olsbye, K.P. Lillerud, C. Atzori, S. Bordiga, C. Lamberti "Modulator effect in UiO-66-NDC (1, 4-naphthalenedicarboxilic acid) synthesis and comparison with UiO-67-NDC isoreticular MOFs"
Crystal Growth & Design
2017
17
(10)
5422–5431 (Journal Cover)
(Impact-factor: 4.425 )
DOI: 10.1021/acs.cgd.7b00892
25.
L. Braglia, E. Borfecchia, L. Maddalena, S. Øien, K. A. Lomachenko, A. L. Bugaev, S. Bordiga, A. V. Soldatov, K. P. Lillerud, C. Lamberti "Exploring structure and reactivity of Cu sites in functionalized UiO-67 MOFs"
Catalysis Today
2017
283
(1)
89–103
(Impact-factor: 4.312 )
DOI: 10.1016/j.cattod.2016.02.039
26.
L. Braglia, E. Borfecchia, A. Martini, A. L. Bugaev, A. V. Soldatov, S. Øien-Ødegaard, B. T. Lønstad-Bleken, U. Olsbye, K. P. Lillerud, K. A. Lomachenko, G. Agostini, M. Manzoli and C. Lamberti "The duality of UiO-67-Pt MOFs: connecting treatment conditions and encapsulated Pt species by operando XAS"
Physical Chemistry Chemical Physics
2017
19
27489-27507
(Impact-factor: 4.123 )
DOI: 10.1039/C7CP05185A
27.
L. Braglia, E. Borfecchia, K. A. Lomachenko, A. L. Bugaev, A. A. Guda, A. V. Soldatov, B. T. Lønstad Bleken, S. Øien, U. Olsbye, K. P. Lillerud, S. Bordiga, G. Agostini, M. Manzoli, C. Lamberti "Tuning Pt and Cu sites population inside functionalized UiO-67 MOF by controlling activation conditions"
Faraday Discuss
2017
201
277-298
(Impact-factor: 3.544 )
DOI: 10.1039/C7FD00024C
28.
V.V. Butova, A.P. Budnyk, E.A. Bulanova, C. Lamberti, A.V. Soldatov "Hydrothermal synthesis of high surface area ZIF-8 with minimal use of TEA"
Solid State Sciences
2017
69
13–21
(Impact-factor: 1.861 )
DOI: 10.1016/j.solidstatesciences.2017.05.002
29.
V.V. Butova, M.A. Soldatov, A.A. Guda, K.A. Lomachenko, and C. Lamberti "Metal-Organic Frameworks: Structure, Properties, Synthesis, and Characterization"
Russ. Chem. Rev.
2016
85
(3)
280-307
(Impact-factor: 3.991 )
DOI: 10.1070/RCR4554
30.
Vera V. Butova, Andrey P. Budnik, Elena A. Bulanova and Alexander V. Soldatov "New microwave-assisted synthesis of ZIF-8"
Mendeleev Commun.
2016
26
43–44
(Impact-factor: 2.098 )
DOI: 10.1016/j.mencom.2016.01.017
31.
A. A. Guda, S. A. Guda, M. A. Soldatov, K. A. Lomachenko, A. L. Bugaev, C. Lamberti, W. Gawelda, C. Bressler, G. Smolentsev, A. V. Soldatov and Y. Joly "Finite difference method accelerated with sparse solvers for structural analysis of the metal-organic complexes"
Journal of Physics: Conference Series
2016
712
(1)
012004
DOI: 10.1088/1742-6596/712/1/012004