Метал-органические каркасные структуры

Metal-organic Frameworks (MOFs)


Metal-organic frameworks (MOFs) are compounds consisting of metal ions or clusters coordinated to organic molecules to form one-, two-, or three-dimensional structures that can be porous. The organic molecules included are sometimes referred to as "struts", and include such examples as 1,4-benzenedicarboxylic acid (BDC).

More formally, a metal–organic framework is a coordination network with organic ligands containing potential voids. A coordination network is a coordination compound extending, through repeating coordination entities, in one dimension, but with cross-links between two or more individual chains, loops, or spiro-links, or a coordination compound extending through repeating coordination entities in two or three dimensions; and finally a coordination polymer is a coordination compound with repeating coordination entities extending in one, two, or three dimensions.

In some cases, the pores are stable during elimination of the guest molecules (often solvents) and could be used for the storage of gases such as hydrogen and carbon dioxide. Other possible applications of MOFs are in gas purification, in gas separation, in catalysis and as sensors

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Some publications


This list contains 12 publications with total Impact-Factor of 49.871

1. Stubbs, A.W., Braglia, L., Borfecchia, E., Meyer, R.J., Román-Leshkov, Y., Lamberti, C., Dincǎ, M. "Selective Catalytic Olefin Epoxidation with Mn(II)-Exchanged MOF-5" ACS Catalysis 2018 8 (1) 596-601 (Impact-factor: 10.614) DOI: 10.1021/acscatal.7b02946  

2. M. Signorile, A. Damin, F. Bonino, V. Crocellà, G. Ricchiardi, C. Lamberti, and S. Bordiga "Computational assessment of relative sites stabilities and site-specific adsorptive properties of Titanium Silicalite-1" Journal of Physical Chemistry 2018 122 (3) 1612-1621 (Impact-factor: 4.536) DOI: 10.1021/acs.jpcc.7b10104

3. S. Waitschat, D. Fröhlich, H. Reinsch, H. Terraschke, K. A. Lomachenko, C. Lamberti, H. Kummer, T. Helling, M. Baumgartner, S. Henninger and N. Stock "Synthesis of M-UiO-66 (M = Zr, Ce or Hf) employing 2,5-pyridinedicarboxylic acid as a linker: Defect chemistry, framework hydrophilisation and sorption properties" Dalton Transactions 2018 47 1062-1070 (Impact-factor: 4.029) DOI: 10.1039/C7DT03641H

4. A.L. Bugaev, A.A. Guda, K.A. Lomachenko, E.G. Kamyshova, M.A Soldatov, G. Kaur, S. Øien-Ødegaard, L. Braglia, A. Lazzarini, M. Manzoli, S. Bordiga, U. Olsbye, K. Petter Lillerud, A.V Soldatov and C. Lamberti "Operando study of palladium nanoparticles inside UiO-67 MOF for catalytic hydrogenation of hydrocarbons" Faraday Discussions 2018 Accepted Manuscript (Impact-factor: 3.588) DOI: 10.1039/C7FD00224F  

5. S. Smolders, K.A. Lomachenko, B. Bueken, A. Struyf, A.L. Bugaev, C. Atzori, N. Stock, C. Lamberti, M. B.J. Roeffaers, D. De Vos "Unravelling the redox-catalytic behavior of Ce4+-MOFs: a XAS study" ChemPhysChem 2018 19 (4) 373-378 (Impact-factor: 3.138) DOI: 10.1002/cphc.201700967  

6. M. Mortén, Ł. Mentel, A. Lazzarini, I. A. Pankin, C. Lamberti, S. Bordiga, V. Crocella, S. Svelle, K. P. Lillerud, U. Olsbye "A systematic study of isomorphically substituted H-MeAlPO-5 materials for the Methanol to Hydrocarbons (MTH) reaction" ChemPhysChem 2018 19 (4) 484-495 (Impact-factor: 3.075) DOI: 10.1002/cphc.201701024

7. E. Gallo, E. Gorelov, A.A. Guda, A.L. Bugaev, F. Bonino, E. Borfecchia, G. Ricchiardi, D. Gianolio, S. Chavan, C. Lamberti "Effect of Molecular Guest Binding on the d–d Transitions of Ni2+ of CPO-27-Ni: A Combined UV–Vis, Resonant-Valence-to-Core X-ray Emission Spectroscopy, and Theoretical Study" Inorganic Chemistry 2017 56 (23) 14408-14425 (Journal Cover) (Impact-factor: 4.857) DOI: 10.1021/acs.inorgchem.7b01471

8. L. Braglia, E. Borfecchia, L. Maddalena, S. Øien, K. A. Lomachenko, A. L. Bugaev, S. Bordiga, A. V. Soldatov, K. P. Lillerud, C. Lamberti "Exploring structure and reactivity of Cu sites in functionalized UiO-67 MOFs" Catalysis Today 2017 283 (1) 89–103 (Impact-factor: 4.312) DOI: 10.1016/j.cattod.2016.02.039  

9. L. Braglia, E. Borfecchia, A. Martini, A. L. Bugaev, A. V. Soldatov, S. Øien-Ødegaard, B. T. Lønstad-Bleken, U. Olsbye, K. P. Lillerud, K. A. Lomachenko, G. Agostini, M. Manzoli and C. Lamberti "The duality of UiO-67-Pt MOFs: connecting treatment conditions and encapsulated Pt species by operando XAS" Physical Chemistry Chemical Physics 2017 19 27489-27507 (Impact-factor: 4.123) DOI: 10.1039/C7CP05185A

10. V.V. Butova, A.P. Budnyk, A.A. Guda, K.A. Lomachenko, A.L. Bugaev, A.V. Soldatov, S.M. Chavan, S. Oien-Odegaard, U. Olsbye, K.P. Lillerud, C. Atzori, S. Bordiga, C. Lamberti "Modulator effect in UiO-66-NDC (1, 4-naphthalenedicarboxilic acid) synthesis and comparison with UiO-67-NDC isoreticular MOFs" Crystal Growth & Design 2017 17 (10) 5422–5431 (Journal Cover) (Impact-factor: 4.055) DOI: 10.1021/acs.cgd.7b00892    

11. L. Braglia, E. Borfecchia, K. A. Lomachenko, A. L. Bugaev, A. A. Guda, A. V. Soldatov, B. T. Lønstad Bleken, S. Øien, U. Olsbye, K. P. Lillerud, S. Bordiga, G. Agostini, M. Manzoli, C. Lamberti "Tuning Pt and Cu sites population inside functionalized UiO-67 MOF by controlling activation conditions" Faraday Discuss 2017 201 277-298 (Impact-factor: 3.544) DOI: 10.1039/C7FD00024C  

12. A. A. Guda, S. A. Guda, M. A. Soldatov, K. A. Lomachenko, A. L. Bugaev, C. Lamberti, W. Gawelda, C. Bressler, G. Smolentsev, A. V. Soldatov and Y. Joly "Finite difference method accelerated with sparse solvers for structural analysis of the metal-organic complexes" Journal of Physics: Conference Series 2016 712 (1) 012004 DOI: 10.1088/1742-6596/712/1/012004