Metal-organic Frameworks (MOFs)
Metal-organic frameworks (MOFs) are compounds consisting of metal ions or clusters coordinated to organic molecules to form one-, two-, or three-dimensional structures that can be porous. The organic molecules included are sometimes referred to as "struts", and include such examples as 1,4-benzenedicarboxylic acid (BDC).
More formally, a metal–organic framework is a coordination network with organic ligands containing potential voids. A coordination network is a coordination compound extending, through repeating coordination entities, in one dimension, but with cross-links between two or more individual chains, loops, or spiro-links, or a coordination compound extending through repeating coordination entities in two or three dimensions; and finally a coordination polymer is a coordination compound with repeating coordination entities extending in one, two, or three dimensions.
In some cases, the pores are stable during elimination of the guest molecules (often solvents) and could be used for the storage of gases such as hydrogen and carbon dioxide. Other possible applications of MOFs are in gas purification, in gas separation, in catalysis and as sensors
This project is succesfull thanks to these guys
N. Van Velthoven, M. Henrion, J. Dallenes, A. Krajnc, A.L. Bugaev, P. Liu, S. Bals, A.V. Soldatov, G. Mali, D.E. De Vos "S,O-Functionalized Metal-Organic Frameworks as Heterogeneous Single-Site Catalysts for the Oxidative Alkenylation of Arenes via C-H activation"
(Impact-factor: 12.221 )
Kirichkov M.V., Bugaev A.L., Skorynina A.A., Butova V.V., Budnyk A.P., Guda A.A., Trigub A.L., Soldatov A.V. "In situ formation and decomposition of β-hydride phase in palladium nanoparticles coated with metal-organic framework"
(Impact-factor: 2.259 )
E. G. Kamyshova, A. A. Skorynina, A. L. Bugaev, C. Lamberti, A.V. Soldatov "Formation and growth of Pd nanoparticles in UiO-67 MOF by in situ EXAFS"
Radiation Physics and Chemistry
(Impact-factor: 1.984 )
A.L. Bugaev, A.A. Skorynina, L. Braglia, K.A. Lomachenko, A.A. Guda, A. Lazzarini, S. Bordiga, U. Olsbye, K.P. Lillerud, A.V. Soldatov, C. Lamberti "Evolution of Pt and Pd species in functionalized UiO-67 metal-organic frameworks"
(Impact-factor: 4.888 )
Guda, A. A.; Guda, S. A.; Lomachenko, K. A.; Soldatov, M. A.; Pankin, I. A.; Soldatov, A. V.; Braglia, L.; Bugaev, A. L.; Martini, A.; Signorile, M.; Groppo, E.; Piovano, A.; Borfecchia, E.; Lamberti, C. "Quantitative structural determination of active sites from in situ and operando XANES spectra: From standard ab initio simulations to chemometric and machine learning approaches"
(Impact-factor: 4.888 )
V.V. Butova, A.P. Budnyk, K.M. Charykov, K.S. Vetlitsyna-Novikova, A.L. Bugaev, A.A. Guda, A. Damin, S.M. Chavan, S. Øien-Ødegaard, K.P. Lillerud, A.V. Soldatov, C. Lamberti "Partial and Complete Substitution of the 1, 4-Benzenedicarboxylate Linker in UiO-66 with 1, 4-Naphthalenedicarboxylate: Synthesis, Characterization, and H2-Adsorption Properties"
(Impact-factor: 4.85 )
T. Lastovina, A. Budnyk, Y. Pimonova, A. Bugaev, V. Dmitriev "Thermally-induced arrangement of cobalt and iron in the ZIF-derived Fe,Co,Zn-N/C catalysts for the oxygen reduction reaction"
International Journal of Hydrogen Energy
(Impact-factor: 4.084 )
Pimonova, Y. A., Budnyk, A. P., Weldegebriel, Y., Bugaev, A. L., Lastovina, T. A. "Iron-/nitrogen-doped electrocatalytically active carbons for the oxygen reduction reaction with low amounts of cobalt"
(Impact-factor: 2.584 )
A.L. Bugaev, A.A. Skorynina, E.G. Kamyshova, K.A. Lomachenko, A.A. Guda, A.V. Soldatov, C. Lamberti "In situ X-ray absorption spectroscopy data during formation of active Pt- and Pd-sites in functionalized UiO-67 metal-organic frameworks"
Data in Brief
K. A. Lomachenko, J. Jacobsen, A. L. Bugaev, C. Atzori,
F. Bonino, S. Bordiga, N. Stock, and C. Lamberti "Exact stoichiometry of Ce(x)Zr(6-x) cornerstones in mixedmetal UiO-66 MOFs revealed by EXAFS spectroscopy"
Journal of the American Chemical Society
(Impact-factor: 14.357 )
Stubbs, A.W., Braglia, L., Borfecchia, E., Meyer, R.J., Román-Leshkov, Y., Lamberti, C., Dincǎ, M. "Selective Catalytic Olefin Epoxidation with Mn(II)-Exchanged MOF-5"
(Impact-factor: 10.614 )
M. Signorile, A. Damin, F. Bonino, V. Crocellà, G. Ricchiardi, C. Lamberti, and S. Bordiga "Computational assessment of relative sites stabilities and site-specific adsorptive properties of Titanium Silicalite-1"
Journal of Physical Chemistry C
(Impact-factor: 4.536 )
S. Waitschat, D. Fröhlich, H. Reinsch, H. Terraschke, K. A. Lomachenko, C. Lamberti, H. Kummer, T. Helling, M. Baumgartner, S. Henninger and N. Stock "Synthesis of M-UiO-66 (M = Zr, Ce or Hf) employing 2,5-pyridinedicarboxylic acid as a linker: Defect chemistry, framework hydrophilisation and sorption properties"
(Impact-factor: 4.029 )
A.L. Bugaev, A.A. Guda, K.A. Lomachenko, E.G. Kamyshova, M.A Soldatov, G. Kaur, S. Øien-Ødegaard, L. Braglia, A. Lazzarini, M. Manzoli, S. Bordiga, U. Olsbye, K. Petter Lillerud, A.V Soldatov and C. Lamberti "Operando study of palladium nanoparticles inside UiO-67 MOF for catalytic hydrogenation of hydrocarbons"
(Impact-factor: 3.427 )
M. Mortén, Ł. Mentel, A. Lazzarini, I. A. Pankin, C. Lamberti, S. Bordiga, V. Crocella, S. Svelle, K. P. Lillerud, U. Olsbye "A systematic study of isomorphically substituted H-MeAlPO-5 materials for the Methanol to Hydrocarbons (MTH) reaction"
(Impact-factor: 3.138 )
S. Smolders, K.A. Lomachenko, B. Bueken, A. Struyf, A.L. Bugaev, C. Atzori, N. Stock, C. Lamberti, M. B.J. Roeffaers, D. De Vos "Unravelling the redox-catalytic behavior of Ce4+-MOFs: a XAS study"
(Impact-factor: 3.138 )
Yulia Podkovyrina, Vera Butova, Elena Bulanova, Andriy Budnyk, Maria Kremennaya, Alexander Soldatov and Carlo Lamberti "Characterization of local atomic structure in Co/Zn based ZIFs by XAFS"
Journal of Physics: Conference Series
E. Gallo, E. Gorelov, A.A. Guda, A.L. Bugaev, F. Bonino, E. Borfecchia, G. Ricchiardi, D. Gianolio, S. Chavan, C. Lamberti "Effect of Molecular Guest Binding on the d–d Transitions of Ni2+ of CPO-27-Ni: A Combined UV–Vis, Resonant-Valence-to-Core X-ray Emission Spectroscopy, and Theoretical Study"
14408-14425 (Journal Cover)
(Impact-factor: 4.857 )
V.V. Butova, A.P. Budnyk, A.A. Guda, K.A. Lomachenko, A.L. Bugaev, A.V. Soldatov, S.M. Chavan, S. Oien-Odegaard, U. Olsbye, K.P. Lillerud, C. Atzori, S. Bordiga, C. Lamberti "Modulator effect in UiO-66-NDC (1, 4-naphthalenedicarboxilic acid) synthesis and comparison with UiO-67-NDC isoreticular MOFs"
Crystal Growth & Design
5422–5431 (Journal Cover)
(Impact-factor: 4.425 )
L. Braglia, E. Borfecchia, L. Maddalena, S. Øien, K. A. Lomachenko, A. L. Bugaev, S. Bordiga, A. V. Soldatov, K. P. Lillerud, C. Lamberti "Exploring structure and reactivity of Cu sites in functionalized UiO-67 MOFs"
(Impact-factor: 4.312 )
L. Braglia, E. Borfecchia, A. Martini, A. L. Bugaev, A. V. Soldatov, S. Øien-Ødegaard, B. T. Lønstad-Bleken, U. Olsbye, K. P. Lillerud, K. A. Lomachenko, G. Agostini, M. Manzoli and C. Lamberti "The duality of UiO-67-Pt MOFs: connecting treatment conditions and encapsulated Pt species by operando XAS"
Physical Chemistry Chemical Physics
(Impact-factor: 4.123 )
L. Braglia, E. Borfecchia, K. A. Lomachenko, A. L. Bugaev, A. A. Guda, A. V. Soldatov, B. T. Lønstad Bleken, S. Øien, U. Olsbye, K. P. Lillerud, S. Bordiga, G. Agostini, M. Manzoli, C. Lamberti "Tuning Pt and Cu sites population inside functionalized UiO-67 MOF by controlling activation conditions"
(Impact-factor: 3.544 )
V.V. Butova, A.P. Budnyk, E.A. Bulanova, C. Lamberti, A.V. Soldatov "Hydrothermal synthesis of high surface area ZIF-8 with minimal use of TEA"
Solid State Sciences
(Impact-factor: 1.861 )
V.V. Butova, M.A. Soldatov, A.A. Guda, K.A. Lomachenko, and C. Lamberti "Metal-Organic Frameworks: Structure, Properties, Synthesis, and Characterization"
Russ. Chem. Rev.
(Impact-factor: 3.991 )
Vera V. Butova, Andrey P. Budnik, Elena A. Bulanova and Alexander V. Soldatov "New microwave-assisted synthesis of ZIF-8"
(Impact-factor: 2.098 )
A. A. Guda, S. A. Guda, M. A. Soldatov, K. A. Lomachenko, A. L. Bugaev, C. Lamberti, W. Gawelda, C. Bressler, G. Smolentsev, A. V. Soldatov and Y. Joly "Finite difference method accelerated with sparse solvers for structural analysis of the metal-organic complexes"
Journal of Physics: Conference Series