Our research paper was selected for the cover of Crystal Growth & Design (ACS)04.10.2017
Our research paper "Modulator Effect in UiO-66-NDC (1,4-Naphthalenedicarboxylic Acid) Synthesis and Comparison with UiO-67-NDC Isoreticular Metal–Organic Frameworks" was selected for the cover of Crystal Growth & Design
UiO-66 type metal-organic framework (MOF) with a 1,4-naphthalenedicarboxylic acid (NDC) linker was synthesized using various amounts of benzoic acid as a modulator. It was shown that this modulator leads to defect formation, like missing linkers and secondary building units, in the MOF structure. It improves specific surface area and crystal size, and reduces thermal stability at the same time. The fraction of benzene-carboxylic-substituted linkers can be tuned up to 50%.
Vera V Butova, Andriy P Budnyk, Alexander A Guda, Kirill A Lomachenko, Aram L Bugaev, Alexander V Soldatov, Sachin M Chavan, Sigurd Oien-Odegaard, Unni Olsbye, Karl Petter Lillerud, Cesare Atzori, Silvia Bordiga, Carlo Lamberti "Modulator effect in UiO-66-NDC (1, 4-naphthalenedicarboxilic acid) synthesis and comparison with UiO-67-NDC isoreticular MOFs" Crystal Growth & Design 2017 17 (10) 5422–5431